Electrolytic stripping of tin in an acid fluoborate electrolyte by J. G. Groetsch

Cover of: Electrolytic stripping of tin in an acid fluoborate electrolyte | J. G. Groetsch

Published by U.S. Dept. of the Interior, Bureau of Mines in [Washington, D.C.] .

Written in English

Read online

Subjects:

  • Tinplate -- Detinning.,
  • Fluoborates.,
  • Electrolytes.

Edition Notes

Includes bibliographical references.

Book details

Statementby J.G. Groetsch, Jr., R.C. Gabler, Jr., and D.A. Wilson.
SeriesReport of investigations ;, 8887, Report of investigations (United States. Bureau of Mines) ;, 8887.
ContributionsGabler, Robert C., Wilson, Donald A.
Classifications
LC ClassificationsTN23 .U43 no. 8887, TS590 .U43 no. 8887
The Physical Object
Pagination9 p. :
ID Numbers
Open LibraryOL2998631M
LC Control Number84600092

Download Electrolytic stripping of tin in an acid fluoborate electrolyte

DETERMINING ELECTROLYTE COMPOSITION Electrolytic removal of Sn using an aqueous stannous fluoborate-fluoboric acid electrolyte was evaluated using op­ erating conditions similar to those used to pla te Sn on steel (9).

The cell us es a pure Sn anode. The-variables studied were cathode current efficiency, currentCited by: 2. Additional Physical Format: Online version: Groetsch, J.G. (John G.). Electrolytic stripping of tin in an acid fluoborate electrolyte. [Washington, D.C.]: U.S. Dept. The Sn in MSW magnetics makes this material difficult to recycle to the steel industry.

An electrolytic method using stannous fluoborate-fluoboric acid for removing Sn was evaluated. Optimum concentrations of Sn in the electrolyte and the effects of impurities such as Al, Cu, Fe, and Pb on Sn recovery from the electrolyte were evaluated.

Electrolytic stripping of tin in an acid fluoborate electrolyte / By J. (John G.) Groetsch, Donald A. Wilson and Robert C. Gabler. Abstract. Includes bibliographical of. The Sn in MSW magnetics makes this material difficult to recycle to the steel industry. An electrolytic method using stannous fluoborate-fluoboric acid for removing Sn was evaluated.

Optimum concentrations of Sn in the electrolyte and the effects of impurities such as Al, Cu, Fe, and Pb on Sn recovery from the electrolyte were by: 2.

An electrolytic method using stannous fluoborate - fluoboric acid for removing tin was evaluated on a laboratory scale. Optimum concentrations of tin in the electrolyte and the effects of impurities such as aluminum, copper, iron, and lead on tin removal from the electrolyte Cited by: 1.

Electrolytic refining: It is the process of refining of metal in which impure metal is made the anode and a thin strip of pure metal is made the cathode.A solution of metal salt is used as an electrolyte. The apparatus is shown in the figure given below. When electric current is passed through the electrolyte, the impure metal from the anode is dissolved in the electrolyte and.

Electroplating and Metal Finishing concerns itself with the development and applications of composites and non metallic coatings. These coatings are used for decorative, protective and functional application.

Some of the other common metal surface finishing technologies are phosphating, pickling, electroforming, powder coating etc. Electroplating is 4/5(1). Tin SLOTOTIN MT is a sulphuric acid-based electrolyte for the deposition of silky-matt tin coatings.

For acidic matt tin electrolytes an unusual-ly good covering power combined with an excellent solderability are the specific features of this process. The applications relate to tin plating of electronic or electrotechnical Size: KB.

Additive-effects during plating in acid tin methanesulfonate electrolytes Article in Electrochimica Acta 49(25) October with Reads How we measure 'reads'. Electrolyte Experiments Determining Electrolyte Composition.

Electrolytic removal of Sn using an aqueous stannous Electrolytic stripping of tin in an acid fluoborate electrolyte book acid electrolyte was evaluated using operating conditions similar to those used to plate Sn on steel.

The cell uses a pure Sn anode. ELECTRODEPOSITION OF COPPER JACK W. D INI AND DEXTER D. SNYDER 1 Copper is the most common metal plated, exclusive of continuous strip plating and nickel [1]. The major uses of electroplated copper are plating on plastics, printed wiring boards, zinc die castings, automotive bumpers, rotogravure rolls, electrorefining, and electroforming [2 File Size: 5MB.

Electrolyte Cathode Ni2+ Ni2+ OH– Cl– Cl– H+ SO 4 2– Figure 1 Basic electrical circuit for electroplating Chapter 2 UNDERSTANDING THE ELECTROPLATING PROCESS Electroplating is an electrolytic process for depositing a layer of metal upon a substrate to enhance the appearance or properties of the component.

Electroplating Electrolytic stripping of tin in an acid fluoborate electrolyte book a form of. F.X. Xiao etal., Additive efects on tin electrodepositing in acid sulfate electrolytes groups []. Until now, most researches focused on us-ing additives in the acid sulfate electrolyte to produce lus-trous or bright deposits, yet the role of organic additives has not been fully understood.

The aim of this work is to study the role of File Size: 2MB. The electrodeposition of tin, at a copper surface, from a tin sulphate (0. mol dm?3) electrolyte containing methanesulphonic acid (12?5 vol.-%) at K has been studied.

You have not provided enough information. What acid. Copper plating or copper stripping. For control or for EPA. For about $36 you can get a subscription to Metal Finishing which includes procedures for wet chemistry testing in its Guide Book.

Electrolytic refining is a process of refining a metal (mainly copper) by the process of electrolysis. As far as the mechanism of the process is concerned, during electrolysis, a large chunk or slab of impure metal is used as the anode with a thin strip of pure metal at the cathode.

USA USA USA USA US A US A US A US A US A US A US A US A US A US A US A US A Authority US United States Prior art keywords metal fluoborate fiuoborates solvent anode Prior art date Legal status Cited by: 2.

Handbook On Electroplating With Manufacture Of Electrochemicals by Dr. Panda, ISBN:Rs. / US$. For copper plating, two types of electrolytic baths are used. In an acid type bath, the solution is made of – gm of copper sulfate and 25 – 35 gm of sulfuric acid per cc of t obtained is thick and rough requiring polishing.

In cyanide bath, solution is made of 25 gm of copper cyanide, 28 gm of sodium cyanide, 6 gm of sodium carbonate and 6 gm of. The present invention relates to a solution for use in the electroplating of tin and tin alloys comprising a basis solution which includes fluoboric acid or an organic sulfonic acid or one of their salts, divalent tin ions, and an antioxidant compound which includes a transition metal selected from the elements of Group IV B, V B or VI B of the Periodic Table in an amount Cited by: Full text of "Cyanide reduction in bright stripping using an electrolytic process: the Robbins Company" See other formats *TO\lCS USE REDUCTION INSTITUTE UMASS/AMHERST 31SDbb Oatl tOMM 1 THE MASSACHUSETTS TOXICS USE REDUCTION INSTITUTE OCT 2 -J ^ CYANIDE REDUCTION IN BRIGHT STRIPPING USING AN ELECTROLYTIC.

Acid based electrolytic cleaning. An ongoing discussion from through Q. I'm in the process of learning more about surface cleaning, finishing, and coating. I'm using the ASM Volume 5 for reference. I was wondering if anyone ever used acid for cathodic electro cleaning of carbon steel.

Electrolytic conductance, (New York, Interscience Publishers, Concerning the correlation of solid metal and non-electrolyte solubilities /, by P. Auer, Electrolytic stripping of tin in an acid fluoborate electrolyte / ([Washington, D.C.]: U.S.

Dept. of the Interior, Bureau of Mines. There is considerable interest in multivalent cation batteries, such as those based on magnesium, calcium or aluminium 1,2,3,4,5,6,7,8,9,10,Most attention has Cited by: Introduction to electrolysis - electrolytes and non-electrolytes Electrolysis is the process of electrically inducing chemical changes in a conducting melt or solution e.g.

splitting an ionic compound into the metal and Size: KB. Electroplating is done by the process of electrodeposition, and involves the formation of an electrolytic cell consisting of the cathode (the object to be plated) and the anode (the metal used for plating), immersed in an electrolytic solution.

The object to be plated and the metal are dipped into the aqueous solution containing the metal ions. As mentioned earlier, the electrolyte used in the tin process for the electrolytic coloring consists of an acid (usually sulfuric), dissolved tin salts, stabilizers, and color enhancers.

The so-called “counter electrodes” used in the coloring bath could be soluble electrodes made of tin, orFile Size: KB.

Suppose 1 mole of electrolyte is present in v ml of solution, then m = v × (where v contains 1 mole of the electrolyte) Whereas M is molar concentration in mol l -1 Then m = M × Units: ohm-1 cm 2 mol -1 (or) S cm2 mol Q3.

What are conductometric titrations. Explain the conductometric titration of strong acid vs strong Size: 1MB. A new high density low porosity graphite anode that is resistant to the corrosive properties of fluoboric acid electrolyte was developed for electrodialysis treatment of the tin, solder and copper fluoborate containing wastewaters.

Fluoboric acid electrolyte was used to rrevent contamination of the products with sulfate ion. electrolyte is an ion conducting material, which can be in the form of an aqueous, molten, or solid solution, while the separator is a membrane that physically pre- vents a direct contact between the two electrodes and allows ions but not electronsFile Size: 1MB.

Abstract: An improved electrolytic bath composition and process for stripping metal deposits from a different basis metal comprising an aqueous solution containing activating halogen compounds, an amine, nitro and/or nitrate stripping component, an inhibiting agent to inhibit attack of the basis metal comprising glucoheptonic acid, malic acid, and mixtures thereof, as.

Electroplating involves passing an electric current through a solution called an electrolyte. This is done by dipping two terminals called electrodes into the electrolyte and connecting them into a circuit with a battery or other power supply. The electrodes and electrolyte are made from carefully chosen elements or compounds.

When the. Electrolysis of Potassium Iodide Electrolysis Reactions Introduction Electrolysis is defined as the decomposition of a substance by means of an electric current.

When an electric current is passed through water containing an electrolyte, the water molecules decompose via an oxidation–reduction reaction. plating, fluoborate plating, gold plating (gilding), cadmium plating, zinc plating, chemical finishing of aluminium, powder coating of aluminium, bright nickel electro plating, copper plating, etc.

This book covers an intensive study of technology of electroplating, phosphating, powder coating and metal finishing. titanium surface. It removes impurities from the metal surface and gives the surface a high luster.

The present work was carried out to identify effective process parameters for electropolshing titanium. Different voltages, agitation speeds, and polishing times were tried in this work.

An electrolyte containing perchloric acid, methanol,File Size: 1MB. Nickel strip cathodes and commercial grade beryllium anodes were used. To avoid contamination by chlorine, an electrolyte of KF - NaF 2 BeF2 was first tried. The current efficiency attained was low; the metal was deposited in a finely- crystalline form and difficulties were experienced in washing off the solidified electrolyte.

Electrochemical stripping analysis is a set of analytical chemistry methods based on voltammetry or potentiometry that are used for quantitative determination of ions in solution.

Stripping voltammetry (anodic, cathodic and adsorptive) have been employed for analysis of organic molecules as well as metal ions.

Carbon paste, glassy carbon paste. The electrolytic tinning of metallic bodies, for example, electro-tinning of steel strip, is conventionally effected by making the surface to be plated the cathode in an aqueous solution of tin salt, such as, stannous sulfate, stannous chloride or stannous fluoborate, in an acid bath and sodium stannate or potassium stannate in an alkaline bath.

Generally accepted as a critical step in most electroplating processes, surface preparation of metals prior to the metal electroplating is presented.

Definition of the clean surface influence of basis metal and the choice of cleaning methods are discussed. Soak, spray, electrolytic, acid. The word “electrolysis” was introduced by Michael Faraday in the 19th century. In chemistry, electrolysis is a method that uses a DC to drive a non-spontaneous chemical reaction.

This technique is commercially significant as a stage in the separation of elements from naturally occurring sources such as ores using an electrolytic cell.The purity of a sample of picric acid, C 6 H 3 N 3 O 7, is determined by controlled-potential coulometry, converting picric acid to triaminophenol, C 6 H 9 N 3 O.

A g sample of picric acid is placed in a mL volumetric flask and diluted to volume.Strong and Weak Electrolytes. STUDY. Flashcards. Learn. Write. Spell. Test. PLAY. Match. Gravity. Created by. hilariolumbreras PLUS. Terms in this set (34) HCl. Hydrochloric acid, Strong Electrolyte, strong acid.

HBr. Hydrobromic acid, strong electrolyte, strong acid. H2SO4. Sulfuric acid, strong acid, strong base Salts containing an alkali.

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